(1-iButyl-1,​5-cyclooctadiene)​dimethylplatinum(II)

m 227

Formula: C14H23Pt

Canonical Smiles: CC(C[C]12=C3[Pt]42(=[C](=C4CC3)CC1)(C)C)C

Inchi: InChI=1S/C12H17.2CH3.Pt/c1-11(2)10-12-8-6-4-3-5-7-9-12;;;/h11H,4,6-7,9-10H2,1-2H3;2*1H3;

Inchikey: FFJBFWGPKMBHFB-UHFFFAOYSA-N

Mass: 386.14

Publication (over 3 years ago)

Authors:

Mirja Enders

Affiliation:

Karlsruhe Institute of Technology, Institute of Organic Chemistry (Stefan Bräse Group)

DOI: 10.14272/FFJBFWGPKMBHFB-UHFFFAOYSA-N

Characterization

Thumb ptme2 ibu cod  1h

NMR/1H/CDCl3/300

1H-NMR (300 MHz, CDCl3): δ = 4.75-4.62 (m, 3 H, CH), 2.46-2.14 (m, 9 H, 4 × CH2, CH), 1.73-1.62 (m, 2 H, CH2), 0.93 (d, 3JHH = 6.2 Hz, 3 H, CH3), 0.74 (d, 3JHH = 6.1 Hz, 3 H, CH3), 0.71 (s d, 2JPtH = 81.6 Hz, 3 H, PtCH3), 0.69 (s d, 2JPtH = 81.3 Hz, 3 H, PtCH3) ppm.

DOI: 10.14272/FFJBFWGPKMBHFB-UHFFFAOYSA-N/NMR/1H/CDCl3/300

Thumb ptme2 ibu  13c

NMR/13C/CDCl3/100

13C-NMR (100 MHz, CDCl3): δ = 119.2 (+, s d, 1JPtC = 50.8 Hz, Cquart), 100.2 (+, s d, 1JPtC = 45.6 Hz, CH), 98.4 (+, s d, 1JPtC = 61.8 Hz, CH), 96.9 (+, s d, 1JPtC = 55.6 Hz, CH), 49.7 (+, CH), 33.5 (-, CH2), 30.2 (-, CH2), 29.6 (-, CH2), 29.1 (-, CH2), 27.8 (-, CH2), 23.8 (+, CH3CH), 21.0 (+, CH3CH), 10.2 (+, s d, 1JPtC = 726 Hz, PtCH3), 3.1 (+, s d, 1JPtC = 694 Hz, PtCH3) ppm.

DOI: 10.14272/FFJBFWGPKMBHFB-UHFFFAOYSA-N/NMR/13C/CDCl3/100


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